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Raoult, Henry y Termodinámica

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Conceptos clave de Raoult, Henry y Gibbs/Helmholtz

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Raoult, Henry y Termodinámica
 

Raoult, Henry y TermodinámicaOnline version

Conceptos clave de Raoult, Henry y Gibbs/Helmholtz

by Mariana Garita Ubaldo
1

En una solución ideal, la presión de vapor total es P_tot = sumatoria de x_i P_i^*.

2

La energía libre de Helmholtz se define como A = U − T S y sus variables naturales son T y V.

3

La constante de Henry es universal e igual para todos los solutos.

4

La Ley de Henry relaciona la presión de vapor de un soluto con su concentración por P_i = k_H,i c_i en disoluciones diluidas.

5

Henry's law es válida para cualquier concentración y presión sin limitación.

6

La Ley de Raoult funciona con precisión en soluciones no ideales sin desviaciones.

7

A depende principalmente de la presión externa y no de T o V.

8

La energía libre de Gibbs se define como G = H − T S.

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