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Cuestionario: Orbitales Moleculares

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Conceptos clave de MO

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Mexico

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Cuestionario: Orbitales Moleculares
 

Cuestionario: Orbitales MolecularesOnline version

Conceptos clave de MO

by EDGAR GUZMAN
1

¿Qué describe la teoría del orbital molecular?

2

¿Qué diferencia un orbital molecular enlazante de uno antienlazante?

3

¿Qué tipo de superposición produce orbitales sigma?

4

¿Los orbitales pi se forman por la superposición de qué tipo de orbitales?

5

¿Qué indica el asterisco en un orbital molecular?

6

¿Qué recomienda la regla de Hund al ocupar orbitales moleculares?

7

¿Qué relación tiene el orden de enlace con la estabilidad?

8

¿Qué sucede cuando dos orbitales atómicos se superponen fuera de fase?

9

¿Qué tipo de MO resulta al traslapar 2p lateralmente?

10

¿Qué indica la geometría de un orbital sigma?

Explicación

La MO describe la molécula como un todo con orbitales moleculares.

La densidad entre núcleos distingue ambos tipos.

Sigma se asocia a superposición a lo largo del eje internuclear.

Los MO pi provienen de z3p o p en orientación lateral.

El asterisco denota antienlace.

Hund: un electrón por orbital antes de aparear.

La estabilidad se vincula al orden de enlace.

Fase opuesta produce antienlace.

Traslape lateral de p genera π.

Sigma tiene simetría cilíndrica.

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